One of my students told me about MadAsMaths by Dr Trifon Madas. She likes the Practice Papers, particularly the way the papers are rated according to their difficulty, see MP1 for example, where papers and solutions for J through to Z are available.
(Post also added to Mathematics for Students).

MadAsMaths question & solution
Not only do all the questions come with full solutions but most have very clear mark schemes too.

MadAsMaths mark scheme example
The papers cover the Pure Mathematics content of the UK A Level course. Note the Special Papers designed for extremely able students; ideal for students capable of the top grades. This is a really valuable collection of questions.
There are further questions and solutions available in the large collection of booklets, originally samples they are free to use. These are pdf files, if you zoom you will see a clear solution as illustrated in the image here. Some of these booklets are aimed at undergraduate students.
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